And that gives you the Gibbs free energy. 就得到了吉布斯自由能。
Especially when you're talking about something like a chemical potential, which is really nothing but the Gibbs free energy. 尤其是当你谈论诸如,化学势之类的东西的时候,实际上这就是吉布斯自由能。
So this is the variable that goes with Gibbs free energy. 所以这就是吉布斯自由能的变量。
Calculation of Gibbs free energy of iron acetylacetone hydrogenating reaction by density functional theory 用密度泛函方法计算乙酰丙酮铁加氢反应的自由能
And I know the Gibbs free energy is just the sum of the chemical potentials, right? 我们知道吉布斯自由能,等于化学势之和,对吗?
And this is the Gibbs free energy per mole. 化学势是一摩尔物质的吉布斯自由能。
OK, now I have this derivative of the Gibbs free energy divided by the temperature. 现在要进行微分,对除以温度之后的吉布斯自由能。
Quantitative estimation of heat capacity, entropy and gibbs free energy of monosubstituted alkanes 单取代烷烃的热容、熵和吉布斯自由能的定量估算
And then we can also write this in terms of the Gibbs free energy for the reaction. 然后我们可以用反应的,吉布斯自由能把它写出来。
The Gibbs free energy. Notice, we could also write, let's rewrite that. 吉布斯自由能,注意,我们还可以这样写,重写一下。
The Gibbs free energy per mole of A in the liquid phase. 液相中的化学势就是,液相中每摩尔A的吉布斯自由能。
Well, we know how Kp depends on temperature, through the Gibbs free energy of the reaction. 好我们知道Kp依赖于温度,通过反应的。
It's the state that has the lowest Gibbs free energy. 它具有最小的吉布斯自由能。
"The entropy of an isolated system can never decrease. '" If the Gibbs Free energy of two bodies are equal, then the two bodies are in equilibrium at constant pressure. 孤立系统的熵永远不会减少“,”如果两个物体的吉布斯自由能相等,那么这两个固体在常压下处于平衡态“。
Per mole, which is just the Gibbs free energy of vaporization. 每摩尔吉布斯自由能,就是汽化的吉布斯自由能。
Who remembers? Gibbs free energy? 有谁记得?吉布斯自由能?
For the Gibbs free energy it was the pressure and the temperature, the number of particles. 对吉布斯自由能是压强,温度和粒子数。
The Study on the Effect of NaCl on the Formation and on the Solubilization Gibbs Free Energy in Microemulsion System 氯化钠对微乳液形成及增溶热力学的影响
And so that led us to the definitions of other energy quantities, the Helmholtz and Gibbs free energy. 这就要求我们定义,其他的和能量相似的物理量,亥姆赫兹和吉布斯自由能。
With respect to pressure, when we know that the variables that we use for Gibbs free energy are pressure and temperature. Right? 对压强求导,你知道吉布斯自由能,的变量是压强和温度?
We learned that the pressure dependence of the Gibbs free energy gives you the pressure dependence for the chemical potential. 我们还知道吉布斯自由能,对压强的依赖关系决定了,化学势对压强的依赖关系。
So this means that they were taking the derivatives of the Gibbs free energy with respect to one of its variables is something that we should know. 这意味着,当我们对吉布斯自由能求它的变量,的偏导数的时候,我们会得到我们以前学过的东西。
And it relates the temperature change in the Gibbs free energy with the enthalpy change. 这个方程把吉布斯自由能中的温度变化,和焓的变化联系起来。
We learned that the chemical potential for a species is the Gibbs free energy for that species divided by the number of moles, this is Gibbs free energy per mole. 化学势等于吉布斯自由,能除以摩尔数,也就是每摩尔的,吉布斯自由能。
Now, the chemical potential, as we saw, was the Gibbs free energy. 现在,化学势,就像我们看到的,等于吉布斯自由能。
So we go back to writing what the Gibbs free energy is. 我们回到吉布斯自由能的表达式。
So we can replace this with the change in Gibbs free energy from going from gas to liquid. 所以这一项我们可以替代它,用从气相到液相变化的吉布斯自由能。
Linear Gibbs free energy relation 线性吉布斯自由能关系
And the Gibbs free energy, TS you can write it as H minus TS. 吉布斯自由能,等于H减去。
So again with the Gibbs free energy, now I see how to determine, if I change the pressure, if I change the temperature by some modest amount, how much is the Gibbs free energy going to change? 再一次通过吉布斯自由能,我知道当我,适当的改变压强和,温度的时候,吉布斯自由能如何变化?